SRSMC UMR 7565


Partenaires

CNRS


Rechercher

Sur ce site

Sur le Web du CNRS


Accueil > Pages Personnelles

Gros Philippe

Directeur de Recherche CNRS 

Directeur SRSMC
Contact : e-mail :philippe.gros@univ-lorraine.fr
Tel : +33(0)383684979
Fax :+33(0)386684785
 
 
 
 

Domaine de recherche


  • Synthèse Hétérocyclique (Ligands, Catalyseurs)


  • Chimie organométallique et de coordination


  • Photovoltaïque hybride

Thèmes de recherche actuels


  • Nouveaux réactifs de métallation (lithiens, ate-complexes)


  • Structure et mécanisme de processus organométalliques


  • Nouvelles méthodologies de couplages bi(het)aryle


  • Cellules solaires DSC (colorants et médiateurs redox)


Responsabilités


  • Porteur de l’ANR blanc ACTIVATE (ANR-08-BLAN-0051-01), partenariat Pr F. Mongin (Université de Rennes)

  • Président de la section Lorraine de la Société Chimique de France et animation scientifique UMR SRSMC


Collaborations


  • Dr Manuel F. Ruiz-Lopez (CBT-SRSMC), Calculs théoriques structure des aggrégats lithiés (DFT, QM/MM)


  • Pr C.A. Bignozzi, Dr S. Caramori (Université de Ferrara, Italie), Cellules photovoltaïques.


  • Dr M. Whittakker, Dr H. Tye (EVOTEC, UK), couplages de Hiyama en série pyridinique.


Parcours


  • DR2-CNRS depuis 2006


  • HDR (2000), Nancy


  • 1994 (CR2-CNRS, Nancy, P. Caubère) puis CR1 en 1998


  • Stage post-doc SNPE (Isochem)-CNRS 1992-1994


  • Doctorat Chimie Organique Fine, 1992, Lyon

Publications

 

2017

Łomzik, M., Mazuryk, O., Rutkowska-Zbik, D., Stochel, G., Gros, P. C., & Brindell, M. (2017). New ruthenium compounds bearing semicarbazone 2-formylopyridine moiety: Playing with auxiliary ligands for tuning the mechanism of biological activity. Journal of Inorganic Biochemistry, 175(Supplement C), 80–91.
toggle visibility
Pierrat, P., Hesse, S., Cebrián, C., & Gros, P. C. (2017). Controlling charge-transfer properties through a microwave-assisted mono- or bis-annulation of dialkynyl-N-(het)arylpyrroles. Org. Biomol. Chem., .
toggle visibility
Sengul, O., Boydas, E. B., Pastore, M., Sharmouk, W., Gros, P. C., Catak, S., & Monari, A. (2017). Probing optical properties of thiophene derivatives for two-photon absorption. Theor Chem Acc, 136(6), 67.
toggle visibility

2016

Cisneros, R., Beley, M., Lapicque, F., & Gros, P. C. (2016). Hydrophilic Ethylene-Glycol-Based Ruthenium Sensitizers for Aqueous Dye-Sensitized Solar Cells. Eur. J. Inorg. Chem., 2016(1), 33–39.
toggle visibility
Liu, L., Duchanois, T., Etienne, T., Monari, A., Beley, M., Assfeld, X., Haacke, stefan, & Gros, P. C. (2016). A new record excited state 3MLCT lifetime for metalorganic iron(II) complexes. Phys. Chem. Chem. Phys., .
toggle visibility
Mazuryk, O., Łomzik, M., Martineau, D., Beley, M., Brindell, M., Stochel, G., & Gros, P. C. (2016). Anticancer activity of ruthenium(II) polypyridine complexes bearing pyrrolidine substituents. Inorganica Chimica Acta, 443, 86–90.
toggle visibility
Pastore, M., Duchanois, T., Liu, L., Monari, A., Assfeld, X., Haacke, S., & Gros, P. C. (2016). Interfacial charge separation and photovoltaic efficiency in Fe(II)-carbene sensitized solar cells. Phys. Chem. Chem. Phys., .
toggle visibility
Sharmoukh, W., Hassan, W. M. I., Gros, P. C., & Allam, N. K. (2016). Design and synthesis of new Ru-complexes as potential photo-sensitizers: experimental and TD-DFT insights. RSC Adv., 6(73), 69647–69657.
toggle visibility

2015

Char, J., Brulé, E., Gros, P. C., Rager, M. - N., Guérineau, V., & Thomas, C. M. (2015). Synthesis of Heterotactic PLA from rac-Lactide using Hetero-Bimetallic Mg/Zn-Li Systems. Journal of Organometallic Chemistry, 796, 47–52.
toggle visibility
Duchanois, T., Etienne, T., Cebrián, C., Liu, L., Monari, A., Beley, M., Assfeld, X., Haacke, S., & Gros, P. C. (2015). An Iron-Based Photosensitizer with Extended Excited-State Lifetime: Photophysical and Photovoltaic Properties. European Journal of Inorganic Chemistry, 2015(14), 2469–2477.
toggle visibility
Francos, J., Gros, P. C., Kennedy, A. R., & O’Hara, C. T. (2015). Structural Studies of (rac)-BIPHEN Organomagnesiates and Intermediates in the Halogen–Metal Exchange of 2-Bromopyridine. Organometallics, 34(11), 2550–2557.
toggle visibility
Gattuso, H., Duchanois, T., Besancenot, V., Barbieux, C., Assfeld, X., Becuwe, P., Gros, P. C., Grandemange, S., & Monari, A. (2015). Interaction of Iron II Complexes with B-DNA. Insights from Molecular Modeling, Spectroscopy, and Cellular Biology. Front. Chem, , 67.
toggle visibility
Sharmoukh, W., Attanzio, A., Busatto, E., Etienne, T., Carli, S., Monari, A., Assfeld, X., Beley, M., Caramori, S., & Gros, P. C. (2015). 2,5-Dithienylpyrrole (DTP) as donor component in DTP-π-A organic sensitizers: photophysical and photovoltaic properties. RSC Adv., 5(6), 4041–4050.
toggle visibility

2014

Beley, M., & Gros, P. C. (2014). Ruthenium Polypyridine Complexes Bearing Pyrroles and π-Extended Analogues. Synthesis, Spectroelectronic, Electrochemical, and Photovoltaic Properties. Organometallics, 33(18), 4590–4606.
toggle visibility
Duchanois, T., Etienne, T., Beley, M., Assfeld, X., Perpète, E. A., Monari, A., & Gros, P. C. (2014). Heteroleptic Pyridyl-Carbene Iron Complexes with Tuneable Electronic Properties. Eur. J. Inorg. Chem., 2014(23), 3747–3753.
toggle visibility
Marquise, N., Bretel, G., Lassagne, F., Chevallier, F., Roisnel, T., Dorcet, V., Halauko, Y. S., Ivashkevich, O. A., Matulis, V. E., Gros, P. C., & Mongin, F. (2014). Deproto-metallation using mixed lithium–zinc and lithium–copper bases and computed CH acidity of 2-substituted quinolines. RSC Adv., 4(38), 19602–19612.
toggle visibility
Noureen, S., Argazzi, R., Monari, A., Beley, M., Assfeld, X., Bignozzi, C. A., Caramori, S., & Gros, P. C. (2014). Novel Ru-based sunlight harvesters bearing dithienylpyrrolo (DTP)-bipyridine ligands: Synthesis, characterization and photovoltaic properties. Dyes and Pigments, 101, 318–328.
toggle visibility
Tilly, D., Chevallier, F., Mongin, F., & Gros, P. C. (2014). Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds. Chem. Rev., 114(2), 1207–1257.
toggle visibility

2013

Bahnous, M., Bouraiou, A., Chelghoum, M., Bouacida, S., Roisnel, T., Smati, F., Bentchouala, C., Gros, P. C., & Belfaitah, A. (2013). Synthesis, crystal structure and antibacterial activity of new highly functionalized ionic compounds based on the imidazole nucleus. Bioorg. Med. Chem. Lett., 23(5), 1274–1278.
toggle visibility
Kadiyala, R. R., Tilly, D., Nagaradja, E., Roisnel, T., Matulis, V. E., Ivashkevich, O. A., Halauko, Y. S., Chevallier, F., Gros, P. C., & Mongin, F. (2013). Computed CH Acidity of Biaryl Compounds and Their Deprotonative Metalation by Using a Mixed Lithium/Zinc-TMP Base. Chemistry – A European Journal, 19(24), 7944–7960.
toggle visibility
Marquise, N., Harford, P. J., Chevallier, F., Roisnel, T., Dorcet, V., Gagez, A. - L., Sablé, S., Picot, L., Thiéry, V., Wheatley, A. E. H., Gros, P. C., & Mongin, F. (2013). Synthesis of azafluorenones and related compounds using deprotocupration–aroylation followed by intramolecular direct arylation. Tetrahedron, 69(47), 10123–10133.
toggle visibility
Marquise, N., Harford, P. J., Chevallier, F., Roisnel, T., Wheatley, A. E. H., Gros, P. C., & Mongin, F. (2013). Efficient two-step access to azafluorenones and related compounds. Tetrahedron Letters, 54(24), 3154–3157.
toggle visibility

2012

Catel, D., Chevallier, F., Mongin, F., & Gros, P. C. (2012). Chiral Organomagnesiates as Dual Reagents for Bromine-Magnesium Exchange of 2-Bromopyridine and Access to Chiral α-Substituted 2-Pyridylcarbinols. European Journal of Organic Chemistry, 2012(1), 53–57.
toggle visibility
Catel, D., Payen, O., Chevallier, F., Mongin, F., & Gros, P. C. (2012). Pyridylmagnesiates: generation by bromine–metal exchange and enantioselective addition to aldehydes. Tetrahedron, 68(21), 4018–4028.
toggle visibility
Dayaker, G., Tilly, D., Chevallier, F., Hilmersson, G., Gros, P. C., & Mongin, F. (2012). Enantioselective Metalation of N,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral Bases. European Journal of Organic Chemistry, 2012(30), 6051–6057.
toggle visibility
Lachaud, F., Jeandon, C., Beley, M., Ruppert, R., Gros, P. C., Monari, A., & Assfeld, X. (2012). Ground and Excited State Properties of New Porphyrin Based Dyads: A Combined Theoretical and Experimental Study. J. Phys. Chem. A, 116(44), 10736–10744.
toggle visibility
Lachaud, F., Jeandon, C., Monari, A., Assfeld, X., Beley, M., Ruppert, R., & Gros, P. C. (2012). New dyads using (metallo)porphyrins as ancillary ligands in polypyridine ruthenium complexes. Synthesis and electronic properties. Dalton Trans., 41(41), 12865–12871.
toggle visibility
Noureen, S., Caramori, S., Monari, A., Assfeld, X., Argazzi, R., Bignozzi, C. A., Beley, M., & Gros, P. C. (2012). Strong PI-delocalization and substitution effect on electronic properties of dithienylpyrrole-containing bipyridine ligands and corresponding ruthenium complexes. Dalton Trans., 41(16), 4833–4844.
toggle visibility
Payen, O., Chevallier, F., Mongin, F., & Gros, P. C. (2012). Straightforward access to enantioenriched pyrazyl alcohols using chiral organomagnesiates. Tetrahedron: Asymmetry, 23(24), 1678–1682.
toggle visibility
Tilly, D., Snégaroff, K., Dayaker, G., Chevallier, F., Gros, P. C., & Mongin, F. (2012). (Chiral) lithium–(magnesium–)zinc and lithium–cobalt combinations as dual reagents for aromatic deproto-metalation and aryl transfer to aldehydes. Tetrahedron, 68(42), 8761–8766.
toggle visibility

2011

Ahmed, M., Noureen, S., Gros, P. C., Guillot, B., & Jelsch, C. (2011). 2,2′-(Ethane-1,2-diyl)bis[2-(5-bromothiophen-2-yl)-1,3-dioxolane] at 100 K refined using a multipolar atom model. Acta Crystallographica Section C Crystal Structure Communications, 67(8), o329–o333.
toggle visibility
Gros, P. C., & Fort, Y. (2011). Dehalogenative and Deprotonative Lithiation of Pyridines: A Second Wind for Trimethylsilylmethylithium (TMSCH2Li). Current Organic Chemistry, 15(14), 2329–2339.
toggle visibility
Louërat, F., Tye, H., Napier, S., Garrigou, M., Whittaker, M., & Gros, P. C. (2011). TBAF-Catalysed silver oxide-mediated cross-coupling of functional trimethysilylpyridines: access to arylpyridines and bihetaryl compounds. Org. Biomol. Chem., 9, 1768–1773.
toggle visibility
Monari, A., Assfeld, X., Beley, M., & Gros, P. C. (2011). Theoretical Study of New Ruthenium-Based Dyes for Dye-Sensitized Solar Cells. J. Phys. Chem. A, 115(15), 3596–3603.
toggle visibility
Snégaroff, K., Nguyen, T. T., Marquise, N., Halauko, Y. S., Harford, P. J., Roisnel, T., Matulis, V. E., Ivashkevich, O. A., Chevallier, F., Wheatley, A. E. H., Gros, P. C., & Mongin, F. (2011). Deprotonative Metalation of Chloro- and Bromopyridines Using Amido-Based Bimetallic Species and Regioselectivity-Computed CH Acidity Relationships. Chem. Eur. J., , 13284–13297.
toggle visibility

2010

Caramori, S., Husson, J., Beley, M., Bignozzi, C.  A., Argazzi, R., & Gros, P.  C. (2010). Combination of Cobalt and Iron Polypyridine Complexes for Improving the Charge Separation and Collection in Ru(terpyridine)2-Sensitised Solar Cells. Chemistry-A European Journal, 16(8), 2611–2618.
toggle visibility
Chau, N. T. T., Meyer, M., Komagawa, S., Chevallier, F., Fort, Y., Uchiyama, M., Mongin, F., & Gros, P. C. (2010). Homoleptic Zincate-Promoted Room-Temperature Halogen-Metal Exchange of Bromopyridines. Chem. Eur. J., 16(41), 12425–12433.
toggle visibility
Dayaker, G., Chevallier, F., Gros, P. C., & Mongin, F. (2010). Deprotonative metalation of substituted aromatics using mixed lithium–cobalt combinations. Tetrahedron, 66(46), 8904–8910.
toggle visibility
Grabulosa, A., Beley, M., & Gros, P. C. (2010). Metallopolymers from ruthenium and iron pyrrole-containing π-extended complexes as model components for solid state solar cells. Inorganica Chimica Acta, 363(7), 1404–1408.
toggle visibility
Khartabil, H. K., Gros, P. C., Fort, Y., & Ruiz-López, M. F. (2010). Metalation of Pyridines with nBuLi−Li−Aminoalkoxide Mixed Aggregates: The Origin of Chemoselectivity. Journal of the American Chemical Society, 132(7), 2410–2416.
toggle visibility
Louerat, F., & Gros, P. C. (2010). Functional polypyridine ligands from copper-mediated room temperature coupling of 4-chloro-2-trimethylsilylpyridine. Tetrahedron Letters, 51(27), 3558–3560.
toggle visibility
Snegaroff, K., Komagawa, S., Yonehara, M., Chevallier, F., Gros, P. C., Uchiyama, M., & Mongin, F. (2010). Lithium Cadmate-Mediated Deprotonative Metalation of Anisole: Experimental and Computational Study. Journal Of Organic Chemistry, 75(9), 3117–3120.
toggle visibility
Snegaroff, K., Komagawa, S., Chevallier, F., Gros, P. C., Golhen, S., Roisnel, T., Uchiyama, M., & Mongin, F. (2010). Deprotonative Metalation of Substituted Benzenes and Heteroaromatics Using Amino/Alkyl Mixed Lithium-Zinc Combinations. Chem. Eur. J., 16(27), 8191–8201.
toggle visibility

Chapitres de Livre

2013

Gros, P. C. (2013). Other stoichiometric metalation reactions on Pyrimidine and Quinazoline in Topics in Heterocyclic Chemistry. (pp. 1–21). Schnürch, M., Mihovilovic, M.D. (Eds.), Springer, 2013, 1-21.
toggle visibility